Selective local nitrogen doping in a TiO2 electrode for enhancing photoelectrochemical water splitting.

Supporting Information Enhanced photoelectrochemical water splitting performance on TiO2 nanotube arrays coated with an ultrathin Nitrogen-doped carbon

Controlled fabrication of Sn/TiO2 nanorods for photoelectrochemical water splitting

In this work, we investigate the controlled fabrication of Sn-doped TiO2 nanorods (Sn/TiO2 NRs) for photoelectrochemical water splitting. Sn is incorporated into the rutile TiO2 nanorods with Sn/Ti molar ratios ranging from 0% to 3% by a simple solvothermal synthesis method. The obtained Sn/TiO2 NRs are single crystalline with a rutile structure. The concentration of Sn in the final nanorods ca...

Enhanced Photocatalytic Activity for H2 Evolution under Irradiation of UV–Vis Light by Au-Modified Nitrogen-Doped TiO2

BACKGROUND PURPOSE Photocatalytic water splitting for hydrogen evolution is a potential way to solve many energy and environmental issues. Developing visible-light-active photocatalysts to efficiently utilize sunlight and finding proper ways to improve photocatalytic activity for H2 evolution have always been hot topics for research. This study attempts to expand the use of sunlight and to enha...

Photovoltage Effects of Sintered IrO2 Nanoparticle Catalysts in Water-Splitting Dye-Sensitized Photoelectrochemical Cells

Water-splitting dye-sensitized photoelectrochemical cells (WSDSPECs) utilize high surface area TiO2 electrodes functionalized with light absorbing sensitizers and water oxidation catalysts. Because water splitting requires vectorial electron transfer from the catalyst to the sensitizer to the TiO2 surface, attaching both sensitizer and catalyst to TiO2 in the correct sequence and stabilizing th...

Simultaneous enhancements in photon absorption and charge transport of bismuth vanadate photoanodes for solar water splitting

n-Type bismuth vanadate has been identified as one of the most promising photoanodes for use in a water-splitting photoelectrochemical cell. The major limitation of BiVO4 is its relatively wide bandgap (∼2.5 eV), which fundamentally limits its solar-to-hydrogen conversion efficiency. Here we show that annealing nanoporous bismuth vanadate electrodes at 350 °C under nitrogen flow can result in n...